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1.
Dissolved pollutants in stormwater are a main contributor to water pollution in urban environments. However, many existing transport models are semi-empirical and only consider one-dimensional flows, which limit their predictive capacity. Combining the shallow water and the advection–diffusion equations, a two-dimensional physically based model is developed for dissolved pollutant transport by adopting the concept of a ‘control layer’. A series of laboratory experiments has been conducted to validate the proposed model, taking into account the effects of buildings and intermittent rainfalls. The predictions are found to be in good agreement with experimental observations, which supports the assumption that the depth of the control layer is constant. Based on the validated model, a parametric study is conducted, focusing on the characteristics of the pollutant distribution and transport rate over the depth. The hyetograph, including the intensity, duration and intermittency, of rainfall event has a significant influence on the pollutant transport rates. The depth of the control layer, rainfall intensity, surface roughness and area length are dominant factors that affect the dissolved pollutant transport. Finally, several perspectives of the new pollutant transport model are discussed. This study contributes to an in-depth understanding of the dissolved pollutant transport processes on impermeable surfaces and urban stormwater management.  相似文献   
2.
南海北部西沙海槽S1站位的岩心柱沉积物中广泛发育自生矿物黄铁矿,其形态以管状为主,且具有内部中空的圈层结构。使用扫描电镜、电子探针、LA-ICP-MS、SIMS等测试方法研究了管状黄铁矿的形态及圈层结构,结果显示: (1)管状黄铁矿发育内部中空的圈层结构,其中内圈层(Ipy)由莓球状黄铁矿呈五角十二面体紧密堆积组成,外圈层(Opy)由晶形较好晶粒较大的八面体黄铁矿组成,并混有沉积碎屑及钙质生物壳体;(2)内圈层和外圈层分别呈现出贫S富Fe和富S贫Fe的特征,其成因是甲烷渗漏造成的局部还原环境使得As进入黄铁矿中导致晶格空缺或被扭曲,从而促进Ni、Co、Cu、Zn、Pb等微量元素的掺入;(3)内圈层、外圈层发生了明显的硫同位素分馏现象,内圈层中 δ34S 平均为-37.8‰,外圈层中 δ34S 平均为-29.3‰。研究认为,管状黄铁矿作为曾经甲烷渗漏的通道,其生长机制可分为3个阶段: (1)气水通道形成阶段: 向上运移的甲烷流体在沉积物孔隙中逐渐形成气水通道;(2)外圈层形成阶段: 当向上运移的甲烷与硫酸盐发生甲烷厌氧氧化时,逐渐形成晶体较大、晶形较好的八面体黄铁矿外圈层;(3)内圈层形成阶段: 随着甲烷浓度逐渐降低,在气水通道中的微生物作用下,剩余甲烷与向下运移的硫酸盐继续反应形成莓球状黄铁矿内圈层。因此,南海北部的泥岩中大量发育的管状黄铁矿常常与地层中甲烷水合物的存在有关。  相似文献   
3.
提出多天线基线网单历元模糊度同步解算法,其具体实现步骤为:1)根据宽巷组合模糊度易于固定的优点,采用附加已知基线长度约束法同步解算各基线的宽巷模糊度,得到dm~cm级精度的近似基线分量;2)将解算得到的各近似基线分量作为约束,同步解算各基线的基频模糊度,以获取mm级精度的基线矢量。该方法的关键在于检验各历元宽巷模糊度解算的正确性,以获取可靠的近似基线分量,为解算各基线的基频模糊度提供准确的基线先验信息。由于动态情况下各历元观测信息比较少,单纯依赖ratio检验不可靠,提出结合基线误差、单位权中误差、基线网模糊度闭合环及ratio值等对多组宽巷模糊度进行检验,避免ratio值设置不当导致模糊度检验中发生纳伪和弃真问题。实测数据结果证明,该处理方法使得模糊度解算的成功率提高1%~2%,可以获取移动平台更丰富的导航信息,提高其服务能力。  相似文献   
4.
Affected by climate change and policy factors, Kazakhstan is the country with the most severe ecological degradation and grassland conflicts in Central Asia. Therefore, studying the state of grassland carrying resources in Kazakhstan is particularly important for understanding the responses of grassland ecosystems to climate change and human activities. Based on Kazakhstan's remote sensing data and animal husbandry statistics, this study analyzes the patterns of changes in grassland ecosystems in Kazakhstan based on the supply and consumption of these ecosystems. The results show that: 1) From 2003 to 2017, the number of livestock raised in Kazakhstan showed a trend of sustained and steady growth. Due to freezing damage, the scale of livestock farming decreased in 2011, but a spatial difference in the livestock farming structure was not obvious. 2) The fluctuation of grassland supply in Kazakhstan has increased, while the consumption due to animal husbandry has also continued to increase, resulting in an increasing pressure on the grassland carrying capacity. 3) Between 2003 and 2017, the overall grassland carrying status of Kazakhstan have been abundant, but the grassland carrying pressure index has shown a steadily increasing trend, the grassland carrying pressure is growing, and it is mainly determined by grassland productivity. The greater pressure in lower Kyzylorda state, the southern Kazakhstan state of the cultivated land and the northern Kazakhstan state has gradually expanded to include the agro-pastoral zone and the semi-desert zone.  相似文献   
5.
6.
利用MGEX(multi-GNSS experiment)发布的BDS卫星差分码偏差(differential code bias, DCB)产品,比较分析不同太阳活动水平下BDS卫星DCB产品的稳定性变化特性,并采用差分自回归移动平均(auto-regressive integrated moving average, ARIMA)时间序列预测模型,实现不同太阳活动水平下BDS卫星DCB的短期预报。结果表明,在太阳活动高年,BDS卫星DCB日解值稳定度、月稳定性均明显低于太阳活动低年,且不同卫星星座类型的BDS卫星DCB稳定性也存在差异;ARIMA时间序列预报结果与MGEX发布值符合程度较好,优于多项式拟合法预测结果。  相似文献   
7.
The extracellular polysaccharide hydrolase-producing strain EP-1 was isolated from seawater and identified as Paenibacillus pabuli. Furthermore, a homogeneous extracellular polysaccharide hydrolase from Paenibacillus pabuli EP-1 was purified by combining ion-exchange chromatography and size exclusion chromatography with a purification fold of 90.69 and recovery of 16.23%. Characterization of the purified polysaccharide hydrolase revealed a molecular mass of 38 k Da and optimum activity at 45℃ and pH 6.0. The polysaccharide hydrolase maintained its stability within a wide range of pH(3.0–12.0) and thermal stability when the temperature was below 50℃. The presence of Hg~(2+), Fe~(2+), Mn~(2+), Co~(2+) and SDS notably decreased hydrolase activity, and organic solvents such as formaldehyde, acetone, DMF and acetonitrile completely inhibited hydrolase activity. The purified hydrolase had no activity on agar, carrageenan, gellan gum, sodium alginate, or starch, but effectively hydrolyzed the polysaccharide from Ulva prolifera. The Km and Vmax values of this hydrolase were 43.84 mg m L~(-1) and 4.33 mg m L~(-1) min~(-1), respectively. The sequence analysis with quantitative time-of-flight mass spectrometry indicated that the hydrolase was an endoglucanase.  相似文献   
8.
In the seismic event classification,determining the seismic features of rockfall is significantly important for the automatic classification of seismic events because of the huge amount of raw data recorded by seismic stations in continuous monitoring. At the same time, the rockfall seismic features are still not completely understood.This study concentrates on the rockfall frequency content, amplitude(ground velocity), seismic waveform and duration analysis, of an artificial rockfall test at Torgiovannetto(a former quarry in Central Italy). A total of 90 blocks were released in the test, and their seismic signals and moving trajectories were recorded by four tri-axial seismic stations and four cameras, respectively. In the analysis processing,all the artificial rockfall signal traces were cut separately and the seismic features were extracted individually and automatically. In this study, the relationships between a) frequency content and impacted materials, b) frequency content and the distance between block releasing position and seismic station(source-receiver distance) were discussed. As a result, we found that the frequency content of rockfall focuses on 10-60 Hz and 80-90 Hz within a source-receiver distance of 200 m, and it is well correlated with impacted material and source-receiver distance. To evaluate the difference between earthquake and rockfall, 23 clear earthquake signals recorded in a seven month-long continuous seismic monitoring, carried out with the four seismic stations, were picked out, according to the Italian national earthquakes database(INGV). On these traces we performed the same analysis as in the artificial rockfall traces, and two parameters were defined to separate rockfall events from earthquake noise. The first one, the amplitude ratio, is related to the amplitude variation of rockfall between two stations and is greater than that of earthquakes, because of the higher attenuation occurring for rockfall events, which consists in high frequencies whereas for earthquakes it consists in low frequencies. The other parameter, the shape of waveform of signal trace, showed a significant difference between rockfall and earthquake and that could be a complementary feature to discriminate between both. This analysis of artificial rockfall is a first step helpful to understand the seismic characteristics of rockfall, and useful for rockfall seismic events classification in seismic monitoring of slope.  相似文献   
9.
以添加不同掺量填料的氯氧镁水泥(MOC)试件为基体,在空气和碳化箱中分别养护至规定龄期,研究碳化对掺加填料MOC力学性能的影响,并与空气环境进行对比,运用XRD和SEM分析碳化后水化产物和微观结构的变化规律。结果表明,28 d龄期内,随着填料掺量的增加MOC试件碳化后的抗折强度均有所增加,碳化后的抗压强度均有提升,碳化过程反应生成了MgCO_3,不同碳化龄期的主要物相均为5Mg(OH)_2·MgCl_2·8H_2O(5相),而掺加填料不影响MOC的水化产物的组成。  相似文献   
10.
甲玛矿床位于冈底斯成矿带东段,是西藏地区最大的铜多金属矿床之一。磁黄铁矿是甲玛矿床最常见的金属矿物之一,其标型特征不仅反映其自身形成环境,对其形成机制和矿床成因也具有指示意义。文章选取产于不同岩性中的磁黄铁矿矿石样品,利用矿相学、X射线衍射和电子探针分析等手段对磁黄铁矿的形态、成分和结构进行了分析研究。研究表明,甲玛矿床的磁黄铁矿主要分布在距离岩体中心较远的矿区远端矽卡岩和角岩中。磁黄铁矿的晶胞参数和粉晶X射线衍射曲线显示矽卡岩中的磁黄铁矿主要为高温六方磁黄铁矿,角岩中的磁黄铁矿为高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体,但主要以低温单斜磁黄铁矿为主。通过对矽卡岩和角岩中的磁黄铁矿进行电子探针测试,结果显示:矽卡岩中的磁黄铁矿中w(Fe)为60.09%~60.71%,平均为60.38%,w(S)为38.18%~38.69%,平均38.35%,化学分子式为Fe_8S_9~Fe_(10)S_(11);角岩中的磁黄铁矿中w(Fe)为59.05%~59.57%,平均为59.10%,w(S)为39.28%~39.95%,平均39.59%,化学分子式为Fe_5S_6~Fe_7S_8。根据以上矿物学特征,笔者进一步探讨了该矿床磁黄铁矿的沉淀机制:炽热的岩浆热液上涌,与碳酸盐岩地层和碎屑岩地层接触发生相互作用,并有大气水的加入,使得成矿流体在角岩中先快速降温,形成高温六方磁黄铁矿和低温单斜磁黄铁矿的交生体。同时,大量的含矿热液形成,并充填于有利的成矿空间(主要为层间破碎带)沉淀成矿,形成矽卡岩矿体,然后流体在矽卡岩矿段中经历缓慢降温,形成高温六方磁黄铁矿。结合矿床地质特征和相关元素地球化学特征,认为甲玛矿床类型为斑岩-矽卡岩型。  相似文献   
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